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Intramolecular Vibrational Energy Redistribution
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Intramolecular Vibrational Energy Redistribution : ウィキペディア英語版
Intramolecular Vibrational Energy Redistribution
Intramolecular Vibrational Energy Redistribution is a process in which energy is redistributed between different quantum states of a vibrationally excited molecule, which is required by successful theories explaining unimolecular reaction rates such as RRKM theory. Such theories assume a full statistical redistribution between all vibrational modes, but restricted redistribution could enable bond selective chemistry for which deposited energy must remain in a particular mode for as long as it takes for the required reaction to take place.
==References==



抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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